Asian Journal of Research in Chemistry

E. E. Ergozhin ¹, B. A. Mukhitdinova ¹, A. I. Nikitina ¹, N. I. Razuvaeva ¹

Affiliations
1 JCS Institute of Chemical Sciences, Named after A. B. Bekturov, 106, Sh. Ualichanov Str., 050010 Almaty, KZ

Abstract

We have studied radical and cationic initiation of monomers on the basis of quinoid derivatives of allylamine by the method of polyarography, and developed optimum conditions of synthesis of polymers, and studied their structure and the basic properties.

Keywords

Allylamine, Benzoquinone, Polarography, Polymerization, Kinetic.

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E. E. Ergozhin ¹, B. A. Mukhitdinova ¹, A. I. Nikitina ¹, N. I. Razuvaeva ¹

Affiliations
1 JCS Institute of Chemical Sciences Named after A. B. Bekturov, 106, Sh. Ualichanov Str., 050010 Almaty, KZ

Abstract

We have studied radical and cationic initiation of monomers on the basis of quinoid derivatives of allylamine by the method of polyarography, and developed optimum conditions of synthesis of polymers, and studied their structure and the basic properties.

Keywords

Allylamine, Benzoquinone, Polarography, Polymerization, Kinetic.

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B. A. Mukhitdinova ¹, E. E. Ergozhin ¹, A. I. Nikitina ¹, K. Kh. Khakimbolatova ¹

Affiliations
1 JSC Institute of Chemical Sciences named after A. B. Bekturov, 106, Sh. Ualichanov Str., 050010 Almaty, KZ

Abstract

The synthesis features and the properties of an aminоquinoid redox-polymer based on Polyethyleneimine and Chloranil have been studied. The structure of a redox-polymer so obtained has been corroborated by elemental analysis and IR-spectroscopy data. The sorption capacity of samples with respect to perrhenate ions has been studied through polarography. Sorption has been observed on the basis of model solutions NH₄ReO₄, at different pH, various concentrations of primary solutions and different duration of exposure. Comparative data in respect of the sorption of perrhenate ions by industrial designs are set forth herein.

Keywords

Quinone, Polyamine, Redox-Polymers, Sorption, Polarography, Rhenium (VII).

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E. E. Ergozhin ¹, B. A. Mukhitdinova ¹, N. P. Bessonova ², T. K. Chalov ¹, A. I. Nikitina ¹

Affiliations
1 ISC, Institute of Chemical Sciences Named After A.B. Bekturov, 106, Sh. Ualichanov Str.,050010 Almaty, KZ
2 ISC, Physical and Chemical Institute Named After L. Ya. Karpov, 3-1/12 by-str. Obucha, 105064, Moscow, RU

Abstract

S,N-containing redox-polymers were synthesized by thermal polymerization of mono- and disubstituted quinoid derivatives of allylamine in the presence of elementary sulphur. Under the sulphur content in spatially linked samples discussed on reaction course, influence of conditions of synthesis on structure and properties of formed oxidation-reduction polymers.

Keywords

Allylamine, Quinone, Sulphur, Polymerization, Polyarography, Oxidation-Reduction Polymers.

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